Synthesis, characterization, and energetic properties of diazido heteroaromatic high-nitrogen CN compound
MHV Huynh, MA Hiskey, DE Chavez…
文献索引：Huynh, My Hang V.; Hiskey, Michael A.; Chavez, David E.; Naud, Darren L.; Gilardi, Richard D. Journal of the American Chemical Society, 2005 , vol. 127, # 36 p. 12537 - 12543
The synthesis, characterization, and energetic properties of diazido heteroaromatic high- nitrogen CN compound, 3, 6-diazido-1, 2, 4, 5-tetrazine (DiAT), are reported. Its normalized heat of formation (NΔ H f), experimentally determined using an additive method, is shown to be the highest positive NΔ H f compared to all other organic molecules. The unexpected azido-tetrazolo tautomerizations and irreversible tetrazolo transformation of DiAT are ...
