Structural effects in solvolytic reactions. 16. The effect of conformation of the cyclopropyl, phenyl, and isopropyl substituents on their electronic contributions to the …
HC Brown, JD Cleveland
文献索引：Brown,H.C.; Cleveland,J.D. Journal of Organic Chemistry, 1976 , vol. 41, p. 1792 - 1799
The effect of conformation on the electronic contribution of the cyclopropyl, phenyl, and isopropyl substituents to an electron-deficient center was examined by placing these substituents in the para position of the tert-cumyl chloride molecule and determining the rates of solvolysis of these tert-cumyl chlorides with no, one, and two rn-methyl groups flanking the para substituent. The results reveal that there is only a small influence of ...
