Tetrahedron

Reactions of triads Se 8 KOH DMSO, Se 8 KOH DMSO, Te KOH HMPA with acetylenes

BA Trofimov, SV Amosova, NK Gurasova, GK Musorin

文献索引：Trofimov, B. A.; Amosova, S. V.; Gusarova, N. K.; Musorin, G. K. Tetrahedron, 1982 , vol. 38, # 5 p. 713 - 718

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被引用次数: 47

摘要

A new general approach to anionic transformations of acetylenes using superbasic media has been developed. It allows series of new reactions which are not undergone by acetylene under conventional conditions. The triads Se8 KOH dimethylsulfoxide (DMSO), Se8 KOH DMSO, Te KOH-hexamethyl-phosphorictriamide (HMPA) are proposed as new effective reagents for the preparation of unsaturated compounds of sulfur, selenium ...