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A NEW STABLE MODIFIED BOROHYDRIDE REAGENT, EFFICIENT REDUCTION OF DIFFERENT FUNCTIONAL GROUPS WITH SULFURATED BARIUM …

H Firouzabadi, M Ghadami

文献索引:Firouzabadi, Habib; Ghadami, Mahboobeh Phosphorus, Sulfur and Silicon and Related Elements, 2000 , vol. 166, p. 83 - 98

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被引用次数: 8

摘要

Abstract Barium and strontium sulfurated borohydrides, Ba (BH2S3) 2, Sr (BH2S3) 2 the two newly introduced modified borohydride agents, are prepared from NaBH2S3, by metathesis reaction with BaCl2 and SrCl2 in good yields. Ba (BH2S3) 2 is more stable and more reactive than Sr (BH2S3) 2. The reducing ability of Ba (BH2S3) 2 for the reduction of aldehydes, ketones, α, β-unsaturated carbonyl compounds, azides, nitro compounds. and ...