Tetrahedron letters

Cyclopropyl carbenoid insertion into alkenylzirconocenes—a convergent synthesis of alkenylcyclopropanes and alkylidenecyclopropanes

E Thomas, AN Kasatkin, RJ Whitby

文献索引：Thomas, Emma; Kasatkin, Alexander N.; Whitby, Richard J. Tetrahedron Letters, 2006 , vol. 47, # 52 p. 9181 - 9185

全文：HTML全文

被引用次数: 13

摘要

The insertion of cyclopropyl carbenoids into alkenylzirconocenes, derived by hydrozirconation of terminal alkynes, affords allylzirconium species which react with protons and isonitriles to afford alkenylcyclopropanes, and with aldehydes to afford alkylidene cyclopropanes. The addition of lithium carbenoid to zirconium occurs with the inversion of the organolithium centre.