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Tetrahedron

Structural properties of dicyclopentenobenzo-cyclobutene, a small ring tris-annelated benzene

JD Korp, RP Thummel, I Bernal

文献索引:Korp,J.D. et al. Tetrahedron, 1977 , vol. 33, p. 3069 - 3075

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被引用次数: 18

摘要

The synthesis of dicyclopententobenzocyclobutene from 1, 1-dicyclopentenyl and dimethyl cyclobutene-1, 2-dicarboxylate is described. Current theories regarding sterically induced aromatic bond alternation would predict that both the σ and π frameworks should show more double bond character exocyclic to the small fused rings. The structural parameters of dicyclopentenobenzocyclobutene have been determined by single crystal X-ray analysis. ...