Tetrahedron

Oxidation of hydroxylamines to nitroxyl radicals with FREMY's salt: Nitroxyl aldehydes

H Schlude

文献索引：Schlude,H. Tetrahedron, 1973 , vol. 29, p. 4007 - 4011

全文：HTML全文

被引用次数: 22

摘要

Derivatives of 1-hydroxy-2, 2, 6, 6-tetramethylpiperidine were oxidized by potassium nitrosodisulfonate (FREMY's salt) to 2, 2, 6, 6-tetramethylpiperidine-1-oxyls. A triphenylphosphine-alkylene reaction, a Grignard reaction, and esterification resulted in derivatives with aldehyde groups.