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Journal of the American Chemical Society

Dehydrochlorination of 1-Trichloro-2-o-chlorophenyl-2-p-chlorophenylethane (o, p'-DDT Isomer) 1

SJ Cristol, HL Haller

文献索引:Cristol; Haller Journal of the American Chemical Society, 1945 , vol. 67, p. 2222

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被引用次数: 7

摘要

In view of the importance of p, p'-DDT as an insecticidal agent, it was of interest to study some of the reactions of the o, p'-DDT isomer. o $'-DDT, when pure, is a reasonably stable compound. It does not eliminate hydrogen chloride upon heating at 115-120 for two hours. Decomposition of o, p'-DDT, like that of p, p '-DDT, 3 is catalyzed by traces of anhydrous ferric chloride; 1 mole of hydrogen chloride is eliminated and the olefin I1 results.* One ...