An efficient convergent synthesis of novel anisotropic adsorbates based on nanometer-sized and tripod-shaped oligophenylenes end-capped with triallylsilyl groups
X Deng, A Mayeux, C Cai
文献索引：Deng, Xiaobin; Mayeux, Aurelie; Cai, Chengzhi Journal of Organic Chemistry, 2002 , vol. 67, # 15 p. 5279 - 5283
This article describes an efficient and convergent synthesis of a novel tripod-shaped oligophenylene compound. The compound consists of three oligophenylene heptamers as the tripod legs and one bromophenyl group as the functional arm, joining at a tetrahedron silicon atom. Each tripod leg is end-capped with a triallylsilyl group for covalently anchoring the molecules on hydrogen-terminated silicon surfaces via hydrosilylation. The compound ...
