Flash photolysis investigation of the reaction of phenylselanyl radicals with hexabutyldistannane

IP Beletskaya, AS Sigeev, VA Kuzmin…

文献索引：Beletskaya, Irina P.; Sigeev, Alexander S.; Kuzmin, Vladimir A.; Tatikolov, Alexander S.; Hevesi, Laszlo Journal of the Chemical Society. Perkin Transactions 2, 2000 , # 1 p. 107 - 109

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摘要

It has been shown earlier that irradiation of a mixture of the diselenides R 2 Se 2 and R′ 2 Se 2 leads to an equilibrium mixture which contains the mixed diselenide RSeSeR′ formed upon recombination of the corresponding radicals. 5 Similarly, tin selenides R 3 SnSePh are formed upon irradiation of a mixture of diphenyl diselenide and hexaalkyldistannanes. 6 Unlike the exchange reaction between two diselenides, this process can serve as a convenient method for the ...