Regioselective synthesis of 1-formylcyclohexenes by one-carbon homologation

JW Huffman, MJ Wu, HH Joyner

文献索引：Huffmann, John W.; Wu, Ming-Jung; Joyner, H. Howard Journal of Organic Chemistry, 1991 , vol. 56, # 17 p. 5224 - 5226

全文：HTML全文

被引用次数: 3

摘要

1 R-MeorMOM cursor to 11-nor-9-carboxy-Ag-tetrahydrocannabinol 3, a human metabolite of Ag-tetrahydrocannabinol, the major active component of marijuana. Although a number of procedures have been described for the preparation of unsaturated aldehydes by one- carbon homologation, 2 only two appeared attractive for the synthesis of 2. One of these, developed by Denmark,% proceeds by conjugate reduction of an enone, trapping the ...