The Journal of Organic Chemistry

Syntheses and NMR spectra of substituted 2-tert-butyladamantan-2-ols

H Duddeck, D Rosenbaum

文献索引：Duddeck, Helmut; Rosenbaum, Doris Journal of Organic Chemistry, 1991 , vol. 56, # 5 p. 1700 - 1707

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被引用次数: 11

摘要

The synthesis of a number of substituted 2-tert-butyladamantan-2-01s from the corresponding ketones is described. In addition to these addition reactions, some unexpected rearrangements-were observed. Reaction mechanisms are proposed to rationalize the experimental results. 13C NMR spectra of some adamantanes are discussed in terms of substituent interaction effects-.