Synthetic Communications

Synthesis of Prostanoids. I. A Highly Convergent Approach to 13-oxi-Prostanoids

JA Noguez, LA Maldonad

文献索引：Noguez,J.A.; Maldonado,L.A. Synthetic Communications, 1976 , vol. 6, p. 39 - 45

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被引用次数: 21

摘要

Abstract At present, synthetic entry to the biologically active 13-oxi-prostanoids involves allylic rearrangement2 or the Wharton inversion sequence3 from their 15-oxi-derivatives. We wish to present now our results on a totally synthetic, highly convergent approach to these compounds (eg 1a and 1b) which uses the conjugate addition-enolate trapping sequence4. Recently, this methodology has been used for construction of a model of the prostanoid ...