Tetrahedron letters

Sila pummerer rearrangement in highly sterically hindered organosilicon compounds: A new route to bis (trimethylsilyl) ketone

…, A Degl'Innocenti, M Ancillotti, G Seconi, P Dembech

文献索引：Ricci, Alfredo; Innocenti, Alessandro Degl'; Ancillotti, Monica; Seconi, Giancarlo; Dembech, Pasquale Tetrahedron Letters, 1986 , vol. 27, # 49 p. 5985 - 5988

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被引用次数: 12

摘要

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... The oxidation of the tris(trimethylsi]yl)methylthio-methane with m-chloroperoxybenzoic acid, leads through a sila-Pummerer rearrangement occurring in unusually mild conditions, to bis(trimethylsilyl)ketone. ... The oxidation of the tris (trimethylsilyl)methylthio-methane, ...