Stereochemistry of organic sulphur compounds. part 14. synthesis and conformation analysis of 1-thioderivatives of 3, 3-dimethyl-2-butanol and its acetates
E Brunet, JL Garcia-Ruano, H Rodrigueza, F Alcudia
文献索引：Brunet, E.; Garcia-Ruano, J. L.; Rodriguez, J. H.; Alcudia, F. Tetrahedron, 1984 , vol. 40, # 21 p. 4433 - 4445
The synthesis and conformational analysis of some thioderivatives But-CHX-CH2Y (X= OH and OAc: Y= SH, SMe, SO2Me and SMe2) are reported. The conformational equilibra have been established from IH-NMR data and high dilution ir studies. All the compounds exhibited almost monoconformational behaviour around the C (1)-C (2) bond, due to strong steric factors. The observed vicinal coupling constants were used to check the different ...
