The N-alkyldithiocarbamato complexes [M (S 2 CNHR) 2](M= Cd (ii) Zn (ii); R= C 2 H 5, C 4 H 9, C 6 H 13, C 12 H 25); their synthesis, thermal decomposition and use …
…, MA Malik, CQ Nguyen, P O'Brien, J Raftery
文献索引：Memon, Ashfaq A.; Afzaal, Mohammad; Malik, Mohammad A.; Nguyen, Chinh Q.; O'Brien, Paul; Raftery, Jim Dalton Transactions, 2006 , # 37 p. 4499 - 4505
A series of N-alkyldithiocarbamato complexes [M (S2CNHR) 2](M= Cd (II), Zn (II); R= C2H5, C4H9, C6H13, C12H25) have been synthesised and characterized. The decomposition of these complexes to sulfates has been investigated, and a mechanism proposed. The structures of [Zn (S2CNHHex) 2],[Cd ((SO4) 2 (NC5H5) 4)] n and [Cd ((SO4) 2 (NC5H5) 2 (H2O) 2)] n have been determined by X-ray single crystal method. The cadmium complex [ ...
