Products, radical intermediates, and hydrogen atom production in the thermal decomposition of 1, 2-dihydronaphthalene

JA Franz, DM Camaioni, RR Beishline…

文献索引：Franz, James A.; Camaioni, Donald M.; Beishline, Robert R.; Dalling, Don K. Journal of Organic Chemistry, 1984 , vol. 49, # 19 p. 3563 - 3570

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被引用次数: 16

摘要

The thermal decomposition of 1, 2-dihydronaphthalene (DHN) at 300 “C produces tetralin, naphthalene, hydrogen, and five Cm hydrocarbon produds (1-5). The isolation of compounds 1-5 from the thermal decomposition of 1, 2-dihydronaphthalene-4-d revealed compounds 1 and 2 to be formed by the addition of a-hydronaphthyl (2HN) to DHN followed by intramolecular cyclization and hydrogen abstraction. Compound 3 waa formed by ...