Thiol??isocyanate??acrylate ternary networks by selective thiol??click chemistry
H Matsushima, J Shin, CN Bowman…
文献索引：Shin, Junghwan; Matsushima, Hironori; Comer, Christopher M.; Bowman, Christopher N.; Hoyle, Charles E. Chemistry of Materials, 2010 , vol. 22, # 8 p. 2616 - 2625
Abstract Thiol-isocyanate-acrylate ternary networks were formed by the combination of thiol- isocyanate coupling, thiol-acrylate Michael addition, and acrylate homopolymerization. This hybrid polymerization reaction sequence was preferentially controlled by using phosphine catalyst systems in combination with photolysis. The reaction kinetics of the phosphine/acrylate thiol-isocyanate coupling reactions were systematically investigated ...
