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Photoreduction of keto carboxylic acid derivatives to oxyacid derivatives catalyzed by ZnTPPS [zinc tetraphenylporphyrintetrasulfonate]-quinolinium-3-carboxamide- …

I Tabushi, S Kugimiya, T Mizutani

文献索引:Tabushi,Iwao; Kugimiya, Shin-ichi; Mizutani, Tadashi Journal of the American Chemical Society, 1983 , vol. 105, # 6 p. 1658 - 1659

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摘要

The synthetic control of absolute stereochemistry of (+)-thienamycin and related, naturally occurring, trans-substituted carbapenem antibiotics has been developed by a number of unique approaches.'However, there is no successful report for the chiral synthesis of naturally occurring cis-substituted carbapenem antibiotics2 and only racemic 6-epi-PS-5 was~ ynthesized.~ We now report a stereocontrolled synthesis of (-)-carpetimycin A that ...