A novel class of amorphous state triphenylamine-based trihydrazones were synthesized by condensation reaction of tris (p-formylphenyl) amine with N-methyl-N-phenyl hydrazine, N, N- diphenylhydrazine, N-1-naphthyl-N-phenyl-hydrazine, and N-2-naphthyl-N-phenyl- hydrazine, respectively, and characterized using different scanning calorimetry (DSC) and cyclic voltammetry (CV).