7??(Dimethylamino) tricyclo [5.2. 2.01, 6] undecene Derivatives from β??Cyclohexenyl β??Dimethylamino??Substituted α, β??Unsaturated Fischer Carbenes

…, T Labahn, A Demeter, KA Zachariasse…

文献索引：Wu, Yao-Ting; Labahn, Thomas; Demeter, Attila; Zachariasse, Klaas A.; De Meijere, Armin European Journal of Organic Chemistry, 2004 , # 21 p. 4483 - 4491

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被引用次数: 1

摘要

Abstract When heated in pyridine at 80 C, pentacarbonyl [(2E)-3-cyclohexenyl-3- (dimethylamino)-1-ethoxy-2-propen-1-ylidene] chromium (1-Cr) and-tungsten (1-W) complexes undergo 6π-electrocyclization and subsequent reductive elimination to yield the cyclohexane-annelated cyclopentadiene 6, which equilibrates by 1, 5-hydrogen shift with its more reactive isomer 7. The latter molecule is efficiently trapped in Diels− Alder reactions ...