Photochemistry of 2, 3-diazabicyclo [2.1. 1] hex-2-ene.. beta. Carbon-carbon cleavage to a stereorandom triplet biradical

MH Chang, DA Dougherty

文献索引：Chang,M.H.; Dougherty,D.A. Journal of the American Chemical Society, 1982 , vol. 104, p. 2333

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被引用次数: 18

摘要

The photochemistry of 1, 2-diazenes (azo compounds) has been intensively studied because of its potential synthetic utility,'the unique dependencies on structural variations, 2 and the theoretical interest in this simple chrom~ phore.~,~ We describe herein the photochemistry of 2, 3-diazabicyclo [2.1. 1] hex-2-ene (1), 5 the smallest and most strained member of the series of homologous bicyclic azoalkanes. This simple compound displays ...