Models for iron-oxo proteins. Structures and properties of FeIIFeIII, ZnIIFeIII, and FeIIGaIII complexes with (. mu.-phenoxo) bis (. mu.-carboxylato) dimetal cores

AS Borovik, V Papaefthymiou, LF Taylor…

文献索引：Borovik, A. S.; Papaefthymiou, Vasilios; Taylor, Lucille F.; Anderson, Oren P.; Que, Lawrence Journal of the American Chemical Society, 1989 , vol. 111, # 16 p. 6183 - 6195

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被引用次数: 148

摘要

Abstract: A series of bimetallic complexes,[M11M'"'BPMP (02CR) 2] X2 where BPMP is the anion of 2, 6-bis [(bis (2-pyridylmethyl) amino) methyl]-4-methylphenol, has been synthesized to provide models for binuclear metal-oxo centers in proteins (1, M= M'= Fe, R= C2H5, X= BPh4; 2, M= M'= Fe, R= C6HS, X= PF6; 3, M= Fe, M'= Ga, R= C2H5, X= BPh4; 4, M= Zn, M'= Fe, R= CH,, X= BPh4; 5, M= Zn, M'= Fe, R= C2H5, X= BPh4). The complexes 1' ...