Tetrahedron: Asymmetry

… olfactory evaluation of the enantiomerically enriched forms of 7, 11-epoxymegastigma-5 (6)-en-9-one and 7, 11-epoxymegastigma-5 (6)-en-9-ols isomers, identified in …

E Brenna, C Fuganti, S Serra

文献索引：Brenna, Elisabetta; Fuganti, Claudio; Serra, Stefano Tetrahedron Asymmetry, 2005 , vol. 16, # 9 p. 1699 - 1704

被引用次数: 18

摘要

A study on the synthesis of the isomers of the natural C-13 norterpenoids derivatives 7, 11- epoxymegastigma-5 (6)-en-9-one and 7, 11-epoxymegastigma-5 (6)-en-9-ols is reported. The latter compounds were prepared from readily available racemic α-ionone and then resolved by mean of lipase-mediated acetylation. The obtained enantiomerically forms were evaluated for their odour properties.