Tetrahedron

Synthetic equivalents to substituted acetylenes in cycloaddition reactions. Dienophilic reactivity of 2-methyl-, 2-phenyl-and 2, 3-trimethylene-1, 4-benzodithiins-1, 4- …

A Giacometti, O De Lucchi, F Dilillo, S Cossu, K Peters…

文献索引：Giacometti, Andrea; Lucchi, Ottorino De; Dilillo, Francisco; Cossu, Sergio; Peters, Karl; et al. Tetrahedron, 1994 , vol. 50, # 26 p. 7913 - 7922

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被引用次数: 3

摘要

Dienophiles 2-methyl-1, 4-benzodithiin-1, 4-tetroxide (3a), 2-phenyl-1, 4-benzodithiin-1, 4- tetroxide (3b) and 2, 3-trimethylene-1, 4-benzodithiin-1, 4-tetroxide (3c) have been prepared with different methods starting from benzene-1, 2-dithiol (1). Their reactivity was tested towards cyclopentadiene, sulfolene, furan and 1, 3-cyclohexadiene. The Diels-Alder adducts to cyclopentadiene were converted into the corresponding unsaturated hydrocarbons, ...