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Journal of fluorine chemistry

Reactions of polyfluoroarenes with hexamethyldisilazane and with 1, 1, 1-trimethyl-N, N,-bis (trimethylsilyl) stannaneamine in the presence of caesium fluoride

AO Miller, GG Furin

文献索引:Miller, Alexey O.; Furin, Georgii G. Journal of Fluorine Chemistry, 1995 , vol. 75, # 2 p. 169 - 172

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被引用次数: 10

摘要

Hexamethyldisilazane and 1, 1, 1-trimethyl-N, N-bis (trimethylsilyl) stannaneamine aminate pentafluoropyridine, octafluorotoluene, pentafluorobenzonitrile, pentafluoronitrobenzene and pentafluorobenzene sulphonyl fluoride in the presence of caesium fluoride with formation of the corresponding perfluorinated aryl amines (ArNH2), diarylamines (Ar2NH) and triarylamines (Ar3N)(where the amine functions are in positions 4 relative to the arene ...