Chemistry of. beta.-(Phosphatoxy) alkyl and. beta.-(Acyloxy) alkyl Radicals. Migration Reactions: Scope and Stereoselectivity of. beta.-(Phosphatoxy) alkyl …

D Crich, Q Yao, GF Filzen

文献索引：Crich, David; Yao, Qingwei; Filzen, G. Fredrick Journal of the American Chemical Society, 1995 , vol. 117, # 46 p. 11455 - 11470

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被引用次数: 43

摘要

Abstract: An in depth study of the mechanism of the P-(phosphat0xy) alkyl radical migration is presented. Examples are presented which define the scope and limitations of the migration and show that, in certain cases, it is highly stereoselective. It is shown that phosphoranyl radicals are not intermediates in this rearrangement. A series of experiments with stereochemically-, leO-, and deuterium-labeled probes indicate that the migration is ...