Novel cyclization by stannyl anion generated from (trimethylsilyl) tributylstannane (Me3SiSnBu3) and fluoride ion. Application to natural product synthesis

…, N Isono, N Kaneta, M Shibasaki

文献索引：Mori, Miwako; Isono, Naohiro; Kaneta, Naotake; Shibasaki, Masakatsu Journal of Organic Chemistry, 1993 , vol. 58, # 11 p. 2972 - 2976

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被引用次数: 45

摘要

In the field of modem synthetic organic chemistry, the stannyl anion is of growing importance. 1 The stannyl anion is usually prepared from organotin halides, 2a hexaorganoditins, 2b~~ and organotin hydridese2d We have found that the stannyl anion can be generated from Me3SiSnBua (1) and R4NXa3 The generated stannyl anion reacts with an aryl or vinyl halide to produce an aryl or vinyl anion, via a halogen-metal ...