Photochemistry of 4-acylisoxazoles

…, LM Hadel, AA Scimone, TA Stevenson

文献索引：Sauers, R. R.; Hadel, L. M.; Scimone, A. A.; Stevenson, T. A. Journal of Organic Chemistry, 1990 , vol. 55, # 13 p. 4011 - 4019

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被引用次数: 27

摘要

The photochemistry of 4-acylisoxazoles 4, 5, 13, 14, and 17 was investigated in a effort to clarify literature contradictions and anomalies and to provide a more detailed picture of the nature and number of intermediates involved in photoreactions of these systems. In contrast to a previous report on the photorearrangement of 14, both oxazoles expected from a 2H- azirine intermediate have been observed. Wavelength studies of 5 and the derived W- ...