En route to dinitroacetylene: nitro (trimethylsilyl) acetylene and nitroacetylene harnessed by dicobalt hexacarbonyl

…, R Zitterbart, PF Pagoria, KPC Vollhardt

文献索引：Windler, G. Kenneth; Zhang, Mao-Xi; Zitterbart, Robert; Pagoria, Philip F.; Vollhardt, K. Peter C. Chemistry - A European Journal, 2012 , vol. 18, # 21 p. 6588 - 6603

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被引用次数: 12

摘要

Abstract Dinitroacetylene and other nitroacetylenes are attractive stoichiometric precursors to high energy-density materials, but suffer from high reactivity and thermal instability. Herein, we report that nitroacetylenes can be dramatically stabilized in the form of their dicobalt hexacarbonyl complexes. In particular, we describe the syntheses and characterization of the first two transition-metal complexes of nitroalkynes,[μ-1-nitro-2-( ...