Darzens Reaction of Acyl Phosphonates with α-Bromo Ketones: Selective Synthesis of cis-and trans-Epoxyphosphonates

AS Demir, M Emrullahoglu, E Pirkin…

文献索引：Wang, Ke; Zhang, Yonghui; Yuan, Chengye Organic and Biomolecular Chemistry, 2003 , vol. 1, # 20 p. 3564 - 3569

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被引用次数: 15

摘要

... of bases at room temperature afford cis- and trans-epoxyphosphonates in good chemical yields and ... most significant C−C, C−O bond-forming processes in synthetic organic chemistry.(8) It ... is added, and the mixture is extracted with ethyl acetate; the combined organic layers are ...