Chlorin photosensitizers sterically designed to prevent self-aggregation

…, KT de Oliveira, MS Baptista, AJ Bortoluzzi…

文献索引：Uchoa, Adjaci F.; De Oliveira, Kleber T.; Baptista, Mauricio S.; Bortoluzzi, Adailton J.; Iamamoto, Yassuko; Serra, Osvaldo A. Journal of Organic Chemistry, 2011 , vol. 76, # 21 p. 8824 - 8832

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被引用次数: 42

摘要

The synthesis and photophysical evaluation of new chlorin derivatives are described. The Diels–Alder reaction between protoporphyrin IX dimethyl ester and substituted maleimides furnishes endo-adducts that completely prevent the self-aggregation of the chlorins. Fluorescence, resonant light scattering (RLS) and 1H NMR experiments, as well as X-ray crystallographic have demonstrated that the configurational arrangement of the ...