Chemical Communications

Covalent attachment and release of small molecules from functional polyphenylene dendrimers

BAG Hammer, M Baumgarten, K Müllen

文献索引：Hammer, Brenton A. G.; Baumgarten, Martin; Muellen, Klaus Chemical Communications, 2014 , vol. 50, # 16 p. 2034 - 2036

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被引用次数: 6

摘要

Herein, we report the synthesis of 2nd generation PPDs functionalized with free thiol moieties within the scaffold, which were used as anchor points for the covalent attachment of guest species (p-nitrophenol derivatives) through the oxidative formation of disulfide linkages. The disulfide bonds were then cleaved under reductive conditions using dithiothreitol to discharge the molecules.