The Journal of Organic Chemistry

Reactions of. alpha.-chloro epoxides. 1. Hydrolysis of 1, 3-dichloropropene oxide

B Gold, T Leuschen

文献索引：Gold, Barry; Leuschen, Thomas Journal of Organic Chemistry, 1981 , vol. 46, # 7 p. 1372 - 1373

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被引用次数: 7

摘要

In a recent paper Kline, Solomon, and Van Duuren studied the hydrolysis and thermolysis of several a-chloro epoxides, including cis-and trans-1, 3-dichloropropene oxide (la and lb, respectively). l They reported that both la and lb afford a-chloroacrylaldehyde (2) upon hydrolysis in pH 7.4 buffer at 37" C with pseudo-first-order rate constants (kH) determined to be 2.4 X min-', respectively. They also indicated that thermolysis of lb at 200" C in xylene ...