Tetrahedron letters

A cyclophane bridged by an inwardly pyramidalized olefin

RA Pascal, ML Carter, MR Johnson, DM Ho

文献索引：Pascal Jr., Robert A.; Carter, Meredith L.; Johnson, Mark R.; Ho, Douglas M. Tetrahedron Letters, 1996 , vol. 37, # 45 p. 8125 - 8128

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被引用次数: 5

摘要

2, 8, 17-Trithia [45, 12][9] metacyclophan-4-ene, a cyclophane with a tertiary olefin strapped across the face of a benzene ring, has been prepared and its X-ray structure determined. The olefin is pyramidalized toward the benzene ring. The X-ray structure of the corresponding saturated phane (in-2, 8, 17-trithia [45, 12][9] metacyclophane, which was synthesized previously) has also been determined. The structure and reactivity of the in- ...