Bulletin of the Chemical Society of Japan

Studies on Unsaturated Organosilicon Compounds. I. Syntheses of Organovinylsilanes by Wurtz-Fittig Reaction

M Kanazashi

文献索引：Kanazashi, M. Bulletin of the Chemical Society of Japan, 1953 , vol. 26, p. 493 - 496

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被引用次数: 41

摘要

(1) Vinyl chloride and organohalosilanes were shown to react with finely divided metallic sodium in ethyl ether, and trimethyl-, dimethyldi-, triethyl-and dimethylphenyl-vinylsilanes were prepared. Of these, dimethyldi-and dimethylphenyl-vinylsilane are new compounds and their physical constants were given.(2) Infrared spectra of these four organovinylsilanes were obtained and certain characteristic absorption bands were discussed.(3) ...