Synthesis of a [{Mono??N??(4??vinylbenzyl)??1, 4, 7??triazacyclononane} 2Hg](OTf) 2 Sandwich Complex, Polymerization of this Monomer with Divinylbenzene, and Hg2+ …

HC Lo, H Chen, RH Fish

文献索引：Lo, H. Christine; Chen, Hong; Fish, Richard H. European Journal of Inorganic Chemistry, 2001 , # 9 p. 2217 - 2220

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被引用次数: 10

摘要

Abstract We have synthesized a novel, 1, 4, 7-triazacyclononane (TACN)-Hg 2+ sandwich monomer,[{mono-N-(4-vinylbenzyl)-1, 4, 7-TACN} 2 Hg](OTf) 2, which was co-polymerized with the cross-linking agent divinylbenzene to form a Hg 2+-ion templated polymer that was demetallated (> 96%) with 6 N HCl, and subsequently found to be highly selective to reintroduced Hg 2+ ions in competition with Cd 2+, Ag+, Pb 2+, Cu 2+, and Fe 3+ ions at ...