Tetrahedron

Regio-and stereoselective reactions between cyclic Baylis–Hillman type adducts and N-nucleophiles and P-nucleophile

E Krawczyk, K Owsianik, A Skowrońska

文献索引：Krawczyk, Ewa; Owsianik, Krzysztof; Skowronska, Aleksandra Tetrahedron, 2005 , vol. 61, # 6 p. 1449 - 1457

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被引用次数: 13

摘要

New important organic compounds multifunctionalized cyclic 6-membered and 7-membered allylic amines, azide and phosphonates have been obtained via regio-and diastereoselective reactions of cyclic Baylis–Hillman type adducts with N-nucleophiles and P-nucleophile. We have found that the reactions proceed by SN2 or SN2′ processes exclusively, or by both processes simultaneously. The SN2′ process occurs with anti ...