Tetrahedron

Spiranes—III: Synthesis of polyspiro compounds consisting of cyclohexane rings

HAP De Jongh, H Wynberg

文献索引：de Jongh,H.A.P.; Wynberg,H. Tetrahedron, 1964 , vol. 20, p. 2553 - 2573

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被引用次数: 13

摘要

Dialkylation of cyclohexanone and spiro [5, 5] undecanones with 1, 5-dibromopentane or 1, 1-bis (2-bromo-ethyl) cyclohexane (IV) gave seven di-, tri-and tetraspiro ketones (V–XI), which embody four new polyspiro ring systems. Four polyspiro ketones could be reduced according to the Wolff-Kishner method giving three new polyspiro hydrocarbons (XXI— XXIII), while reduction with lithium aluminium hydride gave polyspiro alcohols (XXIV and ...