Palladium (II) 3-iminophosphine (3IP) complexes: Active precatalysts for the intermolecular hydroamination of 1, 2-dienes (allenes) and 1, 3-dienes with aliphatic …
G Kuchenbeiser, AR Shaffer, NC Zingales…
文献索引：Kuchenbeiser, Glenn; Shaffer, Andrew R.; Zingales, Nicholas C.; Beck, John F.; Schmidt, Joseph A.R. Journal of Organometallic Chemistry, 2011 , vol. 696, # 1 p. 179 - 187
The synthesis of alicyclic 3-iminophosphine ligands is extended to include a new framework incorporating a cyclohexenyl backbone with an N-aryl imino functionality (3IPAr). Accordingly, a series of palladium (II) complexes employing this new ligand have been synthesized and utilized in the intermolecular hydroamination of 3-methyl-1, 2-butadiene (1, 1-dimethylallene) and 2, 3-dimethyl-1, 3-butadiene with secondary amines. The complex [ ...
