Synthesis of 2, 3, 9, 10, 16, 17, 23, 24-octaalkynylphthalocyanines and the effects of concentration and temperature on their 1H NMR spectra

DS Terekhov, KJM Nolan, CR McArthur…

文献索引：Terekhov, Dmitri S.; Nolan, Kieran J. M.; McArthur, Colin R.; Leznoff, Clifford C. Journal of Organic Chemistry, 1996 , vol. 61, # 9 p. 3034 - 3040

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被引用次数: 133

摘要

The syntheses of 3, 4-and 4, 5-diiodophthalonitriles are described. Coupling of the latter compound with Pd (PPh3) 2Cl2 and 1-octyne, 1-heptyne, 1-hexyne, 1-pentyne, and 3, 3- dimethyl-1-butyne gave a series of 4, 5-dialkynylphthalonitriles. Hydrogenation of 4, 5-bis (1- pentynyl) phthalonitrile and 4, 5-bis (3, 3-dimethyl-1-butynyl) phthalonitrile gave 4, 5- dipentylphthalonitrile and 4, 5-bis (3, 3-dimethylbutyl) phthalonitriles. Condensation of the ...