Organometallics

Reversible insertion reactions of a platinum germylene complex

KE Litz, K Henderson, RW Gourley, MMB Holl

文献索引：Litz, Kyle E.; Henderson, Kenneth; Gourley, Randall W.; Holl, Mark M. Banaszak Organometallics, 1995 , vol. 14, p. 5008 - 5010

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被引用次数: 53

摘要

Summary: Dihydrogen and carbon dioxide react reversibly with the three-coordinate complex (Et3P) zPtGe-[N (SiMed&. These reactions demonstrate the ability of germylenes to act as strong supporting ligands, while introducing new modes of reactivity via formal Ge (II) I