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The free radical addition of thiolacetic acid to some cyclic olefins

FG Bordwell, WA Hewett

文献索引:Bordwell; Hewett Journal of the American Chemical Society, 1957 , vol. 79, p. 3493,3496

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被引用次数: 59

摘要

Radical addition Addition of tliiolacetic acid to cam-However, two thiolacetatcs are cyclohexyl thiolacetate as judged from the composition of the thiol mixture obtained on hydrolysis. tions 1-methylcyclopentene gave about 70% of cis-and 30% of trans-2- methylcyclopentyl thiolacetates. of thiophenol to 1-methylcyclohexene also occurred predominantly in a trans manner. phene, 8-pinene and a-pinene appears to have taken ...