Experimental study and simulation of kinetics of acetophenone hydrosilylation with diphenylsilane in the presence of rhodium complexes in a microreactor

VM Uvarov, ES Borovinskaya, DA de Vekki…

文献索引：Uvarov; Borovinskaya; De Vekki; Reshetilovskii Russian Journal of General Chemistry, 2010 , vol. 80, # 11 p. 2263 - 2273

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被引用次数: 1

摘要

Abstract The hydrosilylation of acetophenone with diphenylsilane in a microreactor in the presence of complexes [Rh (cod) Cl] 2 and [Rh (CO) 2 (μ-Cl)] 2 and (R)-(-)-cis-mirtanyl-and (R)-(+)-bornylamine in situ was studied, the kinetics simulation of the process was performed, and the multicriteria optimization of the process was carried out. The influence of the micro-mixing effect on the reaction rate was revealed. Best results in the microreactor ...