Alkenes as azido precursors for the one-pot synthesis of 1, 2, 3-triazoles catalyzed by copper nanoparticles on activated carbon

F Alonso, Y Moglie, G Radivoy…

文献索引：Alonso, Francisco; Moglie, Yanina; Radivoy, Gabriel; Yus, Miguel Journal of Organic Chemistry, 2013 , vol. 78, # 10 p. 5031 - 5037

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被引用次数: 27

摘要

A one-pot protocol for the synthesis of 1, 2, 3-triazoles has been developed starting from inactivated alkenes and based on two click reactions: the azidosulfenylation of the carbon– carbon double bond and the copper-catalyzed azide–alkyne cycloaddition (CuAAC). High yields of the β-methylsulfanyl triazoles have been attained using CuNPs/C as catalyst, with other commercial copper catalysts being completely inactive. The versatility of the ...