Synthesis, fragmentation, and photorearrangement of neopentyl and adamantyl phosphonates in the 2, 3-oxaphosphabicyclo [2.2. 2] octene system

…, XP Wu, ND Sadanani, I Lukes, AS Ionkin…

文献索引：Quin, Louis D.; Wu, Xiao-Ping; Sadanani, Narayan D.; Lukes, Ivan; Ionkin, Alexey S.; Day, Roberta O. Journal of Organic Chemistry, 1994 , vol. 59, # 1 p. 120 - 129

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被引用次数: 16

摘要

Precursors for the generation of neopentyl and 1-adamantyl metaphosphates were prepared by the insertion of oxygen into a ring carbon-phosphorus bond of some 7- phospbanorbornene derivatives. The stereochemistry of the resulting products, which possess the 2, 3-oxaphosphabicyclo [2.2. 2] octene ring system, was established by NMR spectroscopy, and by X-ray analysis in one case. The 0-insertion (by MCPBA) generally ...