Synthesis, characterization and reactions of (C5H5)(CO) 2Fe: C (CH3) 2+ and (C5H5)(CO) 2Fe: CH-CH: C (CH3) 2+

CP Casey, WH Miles, H Tukada

文献索引：Casey,C.P.; Miles,W.H.; Tukada,H. Journal of the American Chemical Society, 1985 , vol. 107, p. 2924

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被引用次数: 77

摘要

Results Precursors of Dimethylcarbene Complexes. There are three general routes to electrophilic carbene complexes which are not stabilized by an a-heteroatom:(1) the addition of electrophiles to MCRR'X systems, 2-10v12 (2) protonation or alkylation of vinyl metal c~ mplexes~-~~ J~ and (3) a-hydrogen abstraction from metal-alkyl system~.~ J~ For the synthesis of dimethylcarbene complex 1, we investigated the synthesis and reactivity ...