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Australian Journal of Chemistry

Synthesis of the Syributins and Formal Total Synthesis of Syringolide 1.

R Di Florio, MA Rizzacasa

文献索引:Di Florio, Romina; Rizzacasa, Mark A. Australian Journal of Chemistry, 2000 , vol. 53, # 4 p. 327 - 331

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被引用次数: 8

摘要

Abstract A synthesis of syributins 1 (5) and 2 (6) from D-glyceraldehyde acetonide (12) and furans (14) and (15) is described. Compounds (5) and (6) are cometabolites of the novel non- proteinaceous C-glycosidic elicitor molecules the syringolides 1 (1) and 2 (2). Under a variety of acidic conditions, the intermediate butenolides (9) and (10) provided syributins 1 (5) and 2 (6). Similar results have been reported by Honda and coworkers who converted ...