Amination with Pd NHC Complexes: Rate and Computational Studies Involving Substituted Aniline Substrates

…, RDJ Froese, AC Hopkinson, MG Organ

文献索引：Hoi, Ka Hou; Calimsiz, Selcuk; Froese, Robert D. J.; Hopkinson, Alan C.; Organ, Michael G. Chemistry - A European Journal, 2012 , vol. 18, # 1 p. 145 - 151

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被引用次数: 55

摘要

Abstract The amination of aryl chlorides with various aniline derivatives using the N- heterocyclic carbene-based Pd complexes Pd-PEPPSI-IPr and Pd-PEPPSI-IPent (PEPPSI= pyridine, enhanced precatalyst, preparation, stabilization, and initiation; IPr= diisopropylphenylimidazolium derivative; IPent= diisopentylphenylimidazolium derivative) has been studied. Rate studies have shown a reliance on the aryl chloride to be electron ...