Self-assembling nickel clusters form binding sites for alkali metal cations: novel analogs of enolate aggregates
OF Schall, K Robinson, JL Atwood…
文献索引：Schall, Otto F.; Robinson, Kerry; Atwood, Jerry L.; Gokel, George W. Journal of the American Chemical Society, 1993 , vol. 115, # 14 p. 5962 - 5969
Abstract: Salicylaldimine ligands having 3-methoxy or 3-(2-methoxyethoxy) side arms react with NiSO4 or Ni (OAc) 2 to form novel bimetallic cage structures involving ligands, nickel atoms, and one or more types of counteranions. The cluster structures exhibit complexation properties and are of general interest because of their similarity to known alkali organometallic aggregates. Mixed transition metal-alkali metal aggregates of this type are ...
